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src="/homes/images3/laifang.gif" align="absmiddle" width="20"></td> <td class="title">最q来?/td> <td width="50" ></td> </tr> </table> </td> </tr> <tr><td height="200" valign="top" align="center"> </td></tr> </table> </td> </tr> <tr><td height="10"></td></tr> </table> </td> <td width="10"></td> <td width="742" valign="top" align="center"> <table width="742" border="0" cellspacing="0" cellpadding="0"> <tr> <td class="solid-rw"> <table width="742" border="0" cellspacing="0" cellpadding="0"> <tr> <td height="32" class="center_bg"> <table width="100%" border="0" cellspacing="0" cellpadding="0"> <tr> <td width="56" align="center"><img src=/homes/images/yuanchuang.gif border=0></td> <td width="567" align="left"><span class="title">马宏利:慢回Ҏvl不耐压~的成因分析及实跉|?/span>   <font color=#999999>(2020/2/6 20:55:51)</font></td> <td width="119" style="font-family:'宋体';"><img src="/space/images/zhuanlan.jpg" align="absmiddle"> <a href="/space/blog_post.asp" class="link3">发表博文</a></td> </tr> </table> </td> </tr> <tr><td height="" valign="top" align="center"> <table width="98%" border="0" cellspacing="0" cellpadding="0" align="left"> <tr> <td height="8"></td> </tr> <tr><td align="center" height="100" valign="top"> <table width="99%" border="0" cellspacing="0" cellpadding="0" align="center"> <tr><td class=red_2 align=left></td></tr> <tr> <td align="left"> <table width="98%" border="0" cellspacing="0" cellpadding="0" align="center"> <tr> <td class="style_14_666666"> <div class="f401" id="f401"><p><strong class="faqe"><span style="font-size:14px;"><strong class="faqe"><span style="font-size:14px;color:#e53333;">本篇义堂108马宏利原创<span class="faqe">Q?/span>转蝲必须与聚义堂取得联系<span class="faqe">Q?/span>q标明文章出处!q者必IӞ</span></strong><br /><br /> <span style="color:#003399;"> 一、缘?</span></span></strong></p><p><br />  L属于抛货<span class="faqe">Q?/span>q输成本高。ؓ降低q输成本<span class="faqe">Q?/span>许多工厂在客户不是特别强调的情况?span>Q?/span>会压~包装后送货?</p><p><br />  对于普通来说<span class="faqe">Q?/span>包装去除?span>Q?/span>基本能恢复到原来寸?5%左右或以?span>Q?/span>密度高、弹性好的普通几乎能恢复到99%甚至完全恢复?</p><p><br />  但对?strong>慢回Ҏvl?/strong>来说<span class="faqe">Q?/span>情况׃一样了。几乎所有规格的慢回Ҏvl늻q压~、包装、运输后<span class="faqe">Q?/span>会出CU情况:<strong class="faqe">一U是暂时性恢复不?span>Q?/span>但只要不再受?span>Q?/span>l定的时间又_?span>Q?/span>L也能勉强恢复xq原加工寸Q?/strong>W二U情?span>Q?/span><strong class="faqe">xl过_长时?span>Q?/span>也恢复不到或接近原加工尺?span>Q?/span>最l成~陷产品?/strong> </p><p><br />  因此<span class="faqe">Q?/span>一般供应给国内的慢回弹产品<span class="faqe">Q?/span>基本上不采取压羃包装的方式发?span>Q?/span>虽然q输成本l持高位<span class="faqe">Q?/span>但品质量得以保?span>Q?/span>供需双方q可相安无事?</p><p><br />  但对于做出口业务的企业来?span>Q?/span>高昂?a target="_blank">z际q输</a>成本对生产经营带来很大的影响<span class="faqe">Q?/span>因此不得不考虑压羃包装的方式。但l过压羃包装、长途运输后<span class="faqe">Q?/span>L一部分制品在打开包装后恢复不到客L订单规格要求<span class="faqe">Q?/span>被客h?span>Q?/span>此种情况l供需双方都造成一定的损失<span class="faqe">Q?/span>由此造成的N易纠Uƈ不少见?</p><p><strong class="faqe"> <br /> 如何解x问题<span class="faqe">Q?/span>W者分享一下个人的_浅思考和改善措施?</strong></p><p><strong class="faqe">  <br /><span style="font-size:14px;"> <span style="color:#003399;">二、成因分?</span></span></strong></p><p><br />  L的抗压羃能力<span class="faqe">Q?/span>与组成vl늚各种链段的结构、分子间的化学键能、聚合物的结晶性、相分离E度、异氰酸酯的l构、异氰酸酯的使用比例{许多因素有兟?</p><p><br />  <strong class="faqe">1?/strong>慢回Ҏvl|由高分子量的多元醇和低分子量的多元醇与异氰酸酯反应而成。高分子量多元醇形成的YD体U大<span class="faqe">Q?/span>交联密度?span>Q?/span>zd?span>Q?/span>外在表现是既易于压羃<span class="faqe">Q?/span>外加压力撤销后又Ҏ恢复。低分子量多元醇形成的硬D体U小<span class="faqe">Q?/span>交联密度?span>Q?/span>zd?span>Q?/span>外在表现是既难于压羃<span class="faqe">Q?/span>外力撤销后也难于恢复。这U特性ɋL表现Z慢回弹的特征<span class="faqe">Q?/span>也是刉慢回弹L的依据?br /><br />正因为慢回弹L中YD与段性能有异<span class="faqe">Q?/span>那么相段之间有一定的相分R如果链D之间没有相分离<span class="faqe">Q?/span>那vl体在宏观上是一个紧密结合的整体<span class="faqe">Q?/span>׃形成“牵一发而动全n”的现象<span class="faqe">Q?/span>卻I压羃时整体羃?span>Q?/span>释压后整体恢复。但?span>Q?/span>L的微观结构决定了q种情况不能癑ֈ之百辑ֈ。尤其是l成慢回Ҏvl各U链D分子结构不?span>Q?/span>分子量大分布不?span>Q?/span>相分M可避免的存在着。轻微的相分M得外力撤销后的恢复q程?span>Q?/span>部分段因其zd?span>Q?/span>恢复困难而成了“漏|之鱼?span>Q?/span>此漏|之鱼或多或要牵制软段恢复<span class="faqe">Q?/span>最l导致羃水?</p><p><br /> <strong class="faqe"> 2?/strong>段的结晶性比软段?span>Q?/span>也是恢复不好的原因之一。材料都有相似相Ҏ?span>Q?/span>q在慢回Ҏvl里也适用。硬D는于交联点间距q?span>Q?/span>交联密度?span>Q?/span>但Ş成的分子量小<span class="faqe">Q?/span>更Ҏ聚集在一?span>Q?/span>q些聚集在一L含氢物质׃氢键的存?span>Q?/span>材料的结晶性就增强<span class="faqe">Q?/span>l晶性一?span>Q?/span>内聚力就大。经q压~?span>Q?/span>外力改变了链D늚聚集状?span>Q?/span>使极性相q的基团更容易融合在一P像擀面条Ӟ要不停的撒玉c面或高_面在擀开的面片上Q否则卷h再擀?span>Q?/span>面片会速速黏在一P。撤销外力?span>Q?/span>新Ş成的聚集状态由于内聚力强难以恢复到受力前的状?span>Q?/span>D慢回Ҏvl늾水?</p><p><br /><strong class="faqe">  3?/strong>异氰酔R的结构也是媄响慢回弹L抗压性能的因素之一。通常情况下生产块泡慢回弹L用的都是TDI。由于TDI分子中的2个NCO处于2<span class="faqe">Q?/span>4-位和2<span class="faqe">Q?/span>6-?span>Q?/span>它们之间有一定的夹角<span class="faqe">Q?/span>在受力情况下易于变Ş<span class="faqe">Q?/span>其是在热压情况?span>Q?/span>会生大的Ş变和热损?span>Q?/span>q在文胸l上表现的尤其突?span>Q?/span>q些形变恢复h困难了?</p><p><br />  <strong class="faqe">4?/strong>制备慢回Ҏvl|所使用的异氰酸酯的低指C是造成L恢复性不好的原因。普通的异氰酸酯指数都?00以上<span class="faqe">Q?/span>而慢回弹L?span>Q?/span>异氰酔R的指C般在85-95之间<span class="faqe">Q?/span>也就是说<span class="faqe">Q?/span>q有5-15%的羟基没有参与反应。因?span>Q?/span>L体内q没有生成一张整体的大网<span class="faqe">Q?/span>表面看似一个整?span>Q?/span>但内部却有相当一部分链段是是各自独立的?</p><p><strong class="faqe"><br />  <span style="font-size:14px;color:#003399;">三、实跉|?/span> </strong></p><p><br /><span style="color:#e56600;">  </span><strong class="faqe"><span style="color:#e56600;">1?/span><span style="color:#e56600;">选用高EO聚醚Q所谓的胀气聚醚)替代部分慢回弹聚醚?br /><br /> </span></strong>高EO聚醚g<span class="faqe">Q?/span>分子量大<span class="faqe">Q?/span>与异氰酸酯反应后产生的链D?span>Q?/span>分子量大于或接近普通聚醚与异氰酔R反应后生的链段<span class="faqe">Q?/span>减轻了相分离E度<span class="faqe">Q?/span>也减Ml晶性?</p><p>  高EO含量聚醚<span class="faqe">Q?/span>链段柔顺<span class="faqe">Q?/span>可很好的提供慢回Ҏ果。另?span>Q?/span>高EO聚醚的加?span>Q?/span>可有效改善慢回弹L的耐低温性。这cL料市Z有许多品U可以选用<span class="faqe">Q?/span>譬如常州中亚?041<span class="faqe">Q?/span>上v东大?500<span class="faqe">Q?/span>佛_?621/1623<span class="faqe">Q?/span>׃一诺威?001A{?</p><p><br /> <strong class="faqe"><span style="color:#e56600;"> </span><span style="color:#e56600;">2?/span><span style="color:#e56600;">d量聚醚Ҏ的聚酯来提高材料的内聚力?br /><br /> </span></strong>聚酯链段中因为有酯基的存?span>Q?/span>内聚力大<span class="faqe">Q?/span>抗张抗拉效果?span>Q?/span>做成的慢回弹L抗压~性能明显改善。笔者曾?strong>淄博充美</strong>公司的聚醚改性聚酯PM-580来制备慢回弹L<span class="faqe">Q?/span>取得了满意的耐压效果?</p><p><br />  <strong class="faqe"><span style="color:#e56600;">3?/span><span style="color:#e56600;">用少量高官能度高分子量聚醚做交联?span>Q?/span>用部分高zL聚醚替代普通聚醚做慢回式V?br /><br /> </span></strong>q样既打׃链段分布<span class="faqe">Q?/span>又可降低相分ȝ?span>Q?/span>q可提高反应E度<span class="faqe">Q?/span>减轻l晶性。譬如用330N代替部分普通聚?span>Q?/span>加少量上东?佛_的高<a target="_blank">官能度聚?/a>均能提高抗压效果?</p><p><br /><strong class="faqe"><span style="color:#e56600;"> </span><span style="color:#e56600;"> 4?/span><span style="color:#e56600;">用MDI或在TDI中加入MDI?br /></span></strong><strong class="faqe"><span style="color:#e56600;"><br /> </span></strong>׃MDI 的结构与TDI 不一?span>Q?/span>用它生的vl|压性好<span class="faqe">Q?/span>热损失少。如果要用MDI<span class="faqe">Q?/span>最好选用ҎMDIQ粗MDI 支化度高Ҏ闭孔Q?span>Q?/span>譬如万华?019?223Q亨斯迈?412<span class="faqe">Q?/span>也可用液化MDI<span class="faqe">Q?/span>因ؓ液化MDI是分子内环化<span class="faqe">Q?/span>更耐压~。全MDI 发慢回弹L耐压性比UTDI 要好很多<span class="faqe">Q?/span>有许多厂家已l在应用?</p><p><br />  因个人水qx?span>Q?/span>暂时谈到q里。以上所qC供参?span>Q?/span>错误之处<span class="faqe">Q?/span>请各位同仁不吝赐教?<br /><br /><span class="faqe"><strong class="faqe"><span style="font-size:12px;color:#337fe5;">本文作者:马宏?span>Q?/span></span><span style="font-size:12px;color:#337fe5;">88q毕业于青岛U技大学q?/span><span style="font-size:12px;color:#337fe5;">留校L<span class="faqe">Q?/span></span></strong></span><span class="faqe"><strong class="faqe"><span style="font-size:12px;color:#337fe5;">从事聚}酯材料研发?7q前往q东<span class="faqe">Q?/span>从事有机?span>Q?/span>印染助剂研发与生产?4qv在广?span>Q?/span>江 <span class="faqe">Q?/span>江苏从事慢回弹聚醚与开孔剂销售与技术服?span>Q?/span>关于慢回?span>Q?/span>水U慢回弹<span class="faqe">Q?/span>自由泡高回弹<span class="faqe">Q?/span>模塑慢回?span>Q?/span>模塑高回?span>Q?/span>胀气<span class="faqe">Q?/span>垂直泡等产品生斚w的问题可与他联系<span class="faqe">Q?/span>手机P<span style="font-size:16px;"><span style="font-size:14px;">13687636150?/span></span></span><br /><br /></strong><span style="font-size:14px;color:#006600;"><strong class="faqe">马宏利Y泡技术系列文章相关链接:<br /></strong><a target="_blank"><strong class="faqe"><span style="color:#000000;"><span style="color:#64451d;">?/span></span><span style="color:#000000;"><span style="color:#64451d;">谈慢回ҎvlŞ成机理?/span></span></strong></a></span><br /><a target="_blank"><span style="font-size:14px;">?/span><span style="font-size:14px;">?/span><span style="font-size:14px;">谈慢回弹开孔剂?/span></a><br /><a target="_blank"><span style="font-size:14px;">?/span><span style="font-size:14px;">再谈慢回弹开孔剂?/span></a><br /><a target="_blank"><span style="font-size:14px;">?/span><span style="font-size:14px;">慢回Ҏvl配方中料的用?/span></a><br /><a target="_blank"><span style="font-size:14px;">?/span><span style="font-size:14px;">慢回Ҏvl配方设计简论?/span></a><br /><a target="_blank"><span style="font-size:14px;">?/span><span style="font-size:14px;">慢回Ҏvl发泡设备与工艺杂谈?/span></a><span style="font-size:14px;"> </span></span></p></div> </td></tr></table> </td> </tr> <tr><td height="15" align="center"></td></tr> <tr><td height="5"></td></tr> <tr><td height="15" ></td></tr> <tr><td height="15"></td></tr> <tr> <td height="22" class="gray_999999"> <table width="100%" border="0" cellspacing="0" cellpadding="0"> <tr align="left"> <td width="1%"></td> <td width="42%">分类Q?a target='_blank' href=/publog/blog_all.asp?type=3>软应用</a></td> <td width="21%"></td> <td width="17%">评论Q?font class="red_2"></font>?/td> <td width="19%">览Q?font class="red_2"></font>?/td> </tr> </table> </td> </tr> <tr> <td height="22" class="gray_999999"> <table width="100%" border="0" cellspacing="0" cellpadding="0"> <tr align="left"> <td width="1%"></td> <td width="42%">关键词:<a href=/publog/blog_search.asp?type=1&KeyWord=%E6%85%A2%E5%9B%9E%E5%BC%B9 target=_blank><u>慢回?/U></a> <a href=/publog/blog_search.asp?type=1&KeyWord=%E6%B5%B7%E7%BB%B5 target=_blank><u>L</U></a> <a href=/publog/blog_search.asp?type=1&KeyWord=%E4%B8%8D%E8%80%90%E5%8E%8B%E7%BC%A9 target=_blank><u>不耐压~?/U></a> </td> <td width="7%"></td> <td width="50%" colspan="2"></td> </tr> </table> </td> </tr> <tr> <td height="22" class="gray_999999"> <table width="100%" border="0" cellspacing="0" cellpadding="0"> <tr align="left"> <td><div class="bdsharebuttonbox" style="width:500px; margin-left:160px;"><a href="#" class="bds_more" data-cmd="more">分n刎ͼ</a><a href="#" class="bds_qzone" data-cmd="qzone" title="分n到QQI间">QQI间</a><a href="#" class="bds_weixin" data-cmd="weixin" title="分n到微?>微信</a><a href="#" class="bds_tsina" data-cmd="tsina" title="分n到新微?>新浪微博</a><a href="#" class="bds_tqq" data-cmd="tqq" title="分n到腾讯微?>腾讯微博</a><a href="#" class="bds_renren" data-cmd="renren" title="分nCh人网">Zh|?/a></div> </td> </tr> </table> </td> </tr> </table> </td> </tr> <tr> <td height="5"></td> </tr> </table> </td></tr> </table> </td> </tr> </table> <table width="742" border="0" cellspacing="0" cellpadding="0"> <tr> <td height="10"></td> </tr> </table> <table width="742" border="0" cellspacing="0" cellpadding="0"> <tr> <td class="solid-rw"> <table width="742" border="0" cellspacing="0" cellpadding="0"> <tr> <td height="32" class="center_bg"> <table width="100%" border="0" cellspacing="0" cellpadding="0"> <tr> <td width="41" align="center"><img src="/homes/images3/tiezinew.gif" align="absmiddle"></td> <td width="590" class="title" align="left">相关博文</td> <td width="111" style="font-family:'宋体';"><a href="/homes/blogs.asp?id=3415" class="link3">查看所有博?/a></td> </tr> 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