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<tr><td height="" valign="top" align="center"> <table width="98%" border="0" cellspacing="0" cellpadding="0" align="left"> <tr> <td height="8"></td> </tr> <tr><td align="center" height="100" valign="top"> <table width="99%" border="0" cellspacing="0" cellpadding="0" align="center"> <tr><td class=red_2 align=left></td></tr> <tr> <td align="left"> <table width="98%" border="0" cellspacing="0" cellpadding="0" align="center"> <tr> <td class="style_14_666666"> <div class="f401" id="f401"><p>  <br /><span style="font-size:14px;"><strong class="faqe"><span style="font-size:14px;color:#e53333;">本篇义堂108马宏利原创<span class="faqe">Q?/span>转蝲必须与聚义堂取得联系<span class="faqe">Q?/span>q标明文章出处!q者必IӞ</span></strong></span></p><p> <strong class="faqe"><span style="font-size:14px;color:#003399;"><br />  一、概q?/span></strong><span style="color:#003399;"> </span></p><p> <br />  众所周知Q生产vl|Q即使vl开孔率?5%以上Qvl늻l之间的膜仍有许多残留。在光线照射下,可以看到L表面会有星罗布的反光点。此U现象,影响了vl늚观感。尤其对着色vl|_膜的存在Q导致色料本w颜色失真,譬如:黑色不黑Q红色不U?/p><p> <br />  x问题Q许多数L厂在生工艺和配方上做了不少试Q取得了一定效果,但这在根本上不能完全解决问题。有些尝试利弊相当。譬如发黑色l|Q提高黑色色用量,L黑度增加了,成本也随卛_加;另外黑色色浆用量增加Q给发工艺控制带来不利影响。如此大费周折后Q得到的产品依旧“星光点点”。鉴于此Q笔者开发出一U除膜增亮剂Q用以去除vl늆化后D留在经l间的薄膜,l用,Ҏ高vl品质大有帮助?/p><p> <br />  下面Ҏ做些单分享?/p><p> <strong class="faqe"><span style="font-size:14px;"><br /><span style="color:#003399;">  二、薄膜的产生</span></span></strong><span style="color:#003399;"> </span></p><p> <br />  大家知道Qvl|p醚多元醇与异氰酸酯反应得到。在生񔋹LӞq要加一定量的助剂。所用助剂除了催化剂Q还有硅油,如果要着Ԍq需要色?/p><p> <br /><strong class="faqe"><span style="font-size:14px;"> </span><span style="color:#e53333;"><span style="font-size:14px;"> a在vl发泡过E中有三个作用:</span> </span></strong></p><p> <br /> <strong class="faqe"> <span style="color:#e53333;">1、^化作?br /><br />  </span></strong>聚醚、异氰酸酯、水、物理发泡剂、催化剂、色料等׃各自物性的不同Q相互之间不能很好的相容。加入适量有效的硅油后Q就可以让它们相互融合,密切接触。就像两个h要打Ӟ只有他们能互相接触到ҎQ这架才可以打v来?/p><p> <br /> <strong class="faqe"><span style="color:#e53333;"> 2、稳泡作?br />  <br />  </span></strong>在催化剂的作用下Q水与异氰酸酯反应生产的二氧化碳气体Q在反应体系重力作用下,<a href="//www.wopnyc.com.cn/index.asp" target="_blank">聚集</a>h形成气往外逸出;加了物理发剂时Q物理发泡剂也在反应热的作用下挥发聚集成气逸出Q如果此时气泡不能保持一定的E_性,势必出现q排、破泡,一旦ƈh的和破了的泡大C定的E度Q不以支撑整个体系E_Ӟ那么塌发生了Q发泡肯定失败?/p><p> <br />  <strong class="faqe"><span style="color:#e53333;">3、匀泡作?br /><br />  </span></strong>发q程中聚集的气Q尺怸一Q在发反应l束Q凝胶反应也结束时Q硅油的存在会让寸不一的气泡尽可能的归一化,卻I大变小Q小泡变大?/p><p> <br />  当凝胶反应结束时Q孔破裂,形成开孔的|络l构?/p><p> <br />  a的分子结构与用量、锡的用量都Ҏ泡破裂有明显的媄响。如果硅Ҏ性高Q用量大Q那么Ş成的气壁就厚,表面张力大Q在凝胶l束瞬间气酒难以完全破孔,孔壁上的液体也很隑֍时流到vl늻l上去,形成D留的薄膜?/p><p> <br />  锡量大时Q凝胉度快,泡沫壁上的液体黏度增加快Q孔不易破裂,即破裂Q沫壁上的液体也不能完全{Udl络上去Q就会残留下些许薄膜?/p><p> <br />  q些膜在L熟化q程中会减少部分Q但难以完全消除Q因此,{vl늆化完全切割后Q就会看见分布在切割面上的反光膜。这些膜在有色上显得格外明显,对品品质媄响很大,其是黑色工业Q客户对亮点相当挑剔?/p><p> <strong class="faqe"><span style="font-size:14px;"><br />  三、解?/span></strong> </p><p> <strong class="faqe"> <br /><span class="faqe"> <span style="color:#006600;">可以从几个方面着手来?/span><span style="color:#006600;">除?</span></span></strong></p><p> <strong class="faqe"><br /><span style="color:#006600;">  1?/span></strong><span style="color:#006600;">选择zL相对低的硅油和恰当的用量,使发泡后期沫的泡壁变薄Q易于破开?</span></p><p> <strong class="faqe"><br /><span style="color:#006600;">  2?/span></strong><span style="color:#006600;">用酸闭的gq胺代替部分T-9Q把发q程中的凝胶交给T-9Q把后熟化交lgq胺来完成,q样可大大降低壁未破前的粘度,保持泡壁破了之后液体可以最大化的流向vl늻l。减膜D留?</span></p><p> <br /><span style="color:#006600;">  </span><strong class="faqe"><span style="color:#006600;">3?/span></strong><span style="color:#006600;">dL除膜增亮剂,用化学方法除L留膜?</span></p><p> <br /><span style="color:#9933e5;"><strong class="faqe">  </strong><span style="color:#333333;">W者依据界面技术原理,利用有机表面活性剂能降低某些材料表面张力的原理Q选用可反应型有机材料,辅以高脂肪醇,通过合理的制造工艺,成功开发出?strong><span style="font-size:14px;">L除膜增亮剂WM-655Q?/span></strong>该品已应用于黑色vl는产,取得了满意的除膜效果Q在黑色用量相同的情况下,D留膜远q少于未加除膜剂的,黑色度也明显高于不加除膜剂的产品?</span></span></p><p> <br />  Ƣ迎同行交流沟? <br /><br /><br /><strong class="faqe"><span style="color:#337fe5;">  本文作者:马宏?span>Q?/span><span style="font-size:12px;color:#337fe5;">88q毕业于青岛U技大学q?/span></span><span style="font-size:12px;color:#337fe5;">留校L<span class="faqe">Q?/span></span></strong><span class="faqe"><strong class="faqe"><span style="font-size:12px;color:#337fe5;">从事聚}酯材料研发?7q前往q东<span class="faqe">Q?/span>从事有机?span>Q?/span>印染助剂研发与生产?4qv在广?span>Q?/span>江 <span class="faqe">Q?/span>江苏从事慢回弹聚醚与开孔剂销售与技术服?span>Q?/span>关于慢回?span>Q?/span>水U慢回弹<span class="faqe">Q?/span>自由泡高回弹<span class="faqe">Q?/span>模塑慢回?span>Q?/span>模塑高回?span>Q?/span>胀气<span class="faqe">Q?/span>垂直泡等产品生斚w的问题可与他联系<span class="faqe">Q?/span>手机P<span style="font-size:16px;"><span style="font-size:14px;">13687636150?/span></span></span><br /><br /></strong><span style="font-size:14px;color:#006600;"><strong class="faqe">马宏利Y泡技术系列文章相关链接:<br /><span style="color:#64451d;"><a target="_blank">《提高火焰复合ľ_接牢度的理论探讨与实践?/a></span><br /></strong><a target="_blank"><strong class="faqe"><span style="color:#64451d;">?/span><span style="color:#64451d;">慢回Ҏvl不耐压~的成因分析及实跉|索?/span></strong></a><br /><a target="_blank"><strong class="faqe"><span style="color:#000000;"><span style="color:#64451d;">?/span></span><span style="color:#000000;"><span style="color:#64451d;">谈慢回ҎvlŞ成机理?/span></span></strong></a></span><br /><a target="_blank"><span style="font-size:14px;">?/span><span style="font-size:14px;">?/span><span style="font-size:14px;">谈慢回弹开孔剂?/span></a><br /><a target="_blank"><span style="font-size:14px;">?/span><span style="font-size:14px;">再谈慢回弹开孔剂?/span></a><br /><a target="_blank"><span style="font-size:14px;">?/span><span style="font-size:14px;">慢回Ҏvl配方中料的用?/span></a><br /><a target="_blank"><span style="font-size:14px;">?/span><span style="font-size:14px;">慢回Ҏvl配方设计简论?/span></a><br /><a target="_blank"><span style="font-size:14px;">?/span><span style="font-size:14px;">慢回Ҏvl发泡设备与工艺杂谈?/span></a><span style="font-size:14px;"> </span></span></p></div> </td></tr></table> </td> </tr> <tr><td height="15" align="center"></td></tr> <tr><td height="5"></td></tr> <tr><td height="15" ></td></tr> <tr><td height="15"></td></tr> <tr> <td height="22" 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